Published by Pearson (October 3, 2013) © 2014

Joseph Lambert | Scott Gronert | Herbert Shurvell | David Lightner | Robert Graham Cooks
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    ISBN-13: 9781292054056R180

    Organic Structural Spectroscopy ,2nd edition

    Language: English

    Organic Structural Spectroscopy authoritatively presents the fundamentals of all four principal spectroscopic methods: nuclear magnetic resonance spectroscopy, mass spectrometry, infrared spectroscopy, and ultraviolet-visible spectroscopy. Each topic is examined in depth by an experienced author who is a practicing expert in that area. The material is easy to grasp, beginning at the most elementary level and progressing to the level required for organic research. Among many other enhancements, the Second Edition offers an entirely new discussion of mass spectrometry, with comprehensive coverage of new ionization and fragmentation methods, and treatment of NMR from the basics to advanced 2D methods.
    Chapter 1 Introduction
    1-1    The Spectroscopic Approach to Structure Determination
    1-2    Contributions of Different Forms of Spectroscopy
    1-3    The Electromagnetic Spectrum
    1-4    Molecular Weight and Molecular Formula
    1-5    Structural Isomers and Stereoisomers
    Problems

    Part I  NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY

    Chapter 2 Introduction
    2-1    Magnetic Properties of Nuclei
    2-2    The Chemical Shift
    2-3    Excitation and Relaxation
    2-4    Pulsed Experiments
    2-5    The Coupling Constant
    2-6    Quantification and Complex Splitting
    2-7    Commonly Studied Nuclides
    2-8    Dynamic Effects
    2-9    Spectra of Solids
    2-10    Experimental Methods
    Problems
    Tips on Solving NMR Problems
    Bibliography

    Chapter 3 The Chemical Shift
    3-1    Factors That Influence Proton Shifts
    3-2    Proton Chemical Shifts and Structure
    3-3    Medium and Isotope Effects
    3-4    Factors That Influence Carbon Shirts
    3-5    Carbon Chemical Shifts and Structure
    3-6    Tables of Chemical Shifts
    Problems
    Further Tips on Solving NMR Problems
    Bibliography

    Chapter 4 The Coupling Constant
    4-1    First-Order Spectra
    4-2    Chemical and Magnetic Equivalence
    4-3    Signs and Mechanisms
    4-4    Couplings over One Bond
    4-5    Geminal Couplings
    4-6    Vicinal Couplings
    4-7    Long-Range Couplings
    4-8    Spectral Analysis
    4-9    Second-Order Spectra
    4-10    Tables of Coupling Constants
    Problems
    Bibliography

    Chapter 5 Further Topics in One-Dimensional NMR
    5-1    Spin-Lattice and Spin-Spin Relaxation
    5-2    Reactions on the NMR Time Scale
    5-3    Multiple Resonance
    5-4    The Nuclear Overhauser Effect
    5-5    Spectral Editing
    5-6    Sensitivity Enhancement
    5-7    Carbon Connectivity
    5-8    Phase Cycling, Composite Pulses, and Shaped Pulses
    Problems
    Bibliography

    Chapter 6 Two-Dimensional NMR
    6-1    Proton-Proton Correlation Through Coupling
    6-2    Proton-Heteronucleus Correlation
    6-3    Proton-Proton Correlation Through Space or Chemical Exchange
    6-4    Carbon-Carbon Correlation
    6-5    Higher Dimensions
    6-6    Pulsed Field Gradients
    6-7    Summary of Two-Dimensional Methods
    Problems
    Bibliography

    Part II MASS SPECTROMETRY

    Chapter 7 Instrumentation and Theory
    7-1    Introduction
    7-2    Ionization Methods
    7-3    Mass Analysis
    7-4    Sample Preparation

    Chapter 8 Ion Activation and Fragmentation
    8-1    Basic Principles
    8-2    Methods and Energetics    
    8-3    Functional Groups

    Chapter 9 Structural Analysis
    9-1    Molecular Weights
    9-2    Molecular Formula
    9-3    Structures from Fragmentation Patterns
    9-4    Polymers

    Chapter 10 Quantitative Applications
    10-1    Quantification of Analytes
    10-2    Thermochemistry

    Part III VIBRATIONAL SPECTROSCOPY

    Chapter 11 Introduction
    11-1    Introd